To unlock the characters listed below with Wu, fulfill the corresponding requirement listed.

• Da Qiao - Complete either Wu Chapter 4 (Battle of Itsukushima) or Orochi Chapter 4 (Battle of He Fei)
• Gan Ning - Complete Samurai Chapter 5 (Battle of Liang Province)
• Lu Meng - Complete Samurai Chapter 5 (Battle of Liang Province)
• Lu Xun - Complete Shu Chapter 3 (Battle of Nagashino)
• Sun Ce - Complete either Wu Chapter 4 (Battle of Itsukushima) or Orochi Chapter 4 (Battle of He Fei)
• Taishi Ci - Complete Wei Chapter 3 (Battle of Shizugatake)
• Xiao Qiao - Complete Wu Chapter 2 (Battle of Kanegasaki)
• Zhou Yu - Complete Wu Chapter 2 (Battle of Kanegasaki)