To unlock the characters listed, fulfill the corresponding requirement listed.

• Diao Chan - Complete Wu Chapter 8 (Battle of Chi Bi)
• Lu Bu - Complete Wu Chapter 8 (Battle of Chi Bi)
• Meng Huo - Complete Wu Chapter 3 (Battle of Nan Zhong)
• Yuan Shao - Complete Wei Chapter 3 (Battle of Shizugatake)
• Zhang Jiao - Complete Samurai Chapter 1 (Battle of Lou Sang)
• Zhu Rong - Complete Wu Chapter 3 (Battle of Nan Zhong)
• Zuo Ci - Complete Shu Chapter 1 (Battle of Shi Ting)