To unlock the characters listed, fulfill the corresponding requirement listed.

• Dodomekki - Collect 5 ingredients
• Fu Xi - Complete Samurai Chapter 3 (Battle of Hasedo)
• Gyuki - Collect 25 ingredients
• Himiko - Complete Wei Chapter 8 (Battle of Wu Zhang Plains)
• Minamoto no Yoshisune - Complete Wu Chapter 1 (Battle of Ru Xu Kou)
• Shin Orochi - Complete Dramatic Mode
• Sun Wukong - Complete Wei Chapter 8 (Battle of Guan Du)
• Taigong Wang - Complete Shu Chapter 1 (Battle of Shi Ting)
• Taira no Kiyomori - Complete Samurai Chapter 8 (Battle of Sekigahara)