Cao Cao - Clear Musou Mode with 3 Wei characters
Cao Pi - Deafeat Cao Pi within 5 minutes on Sun Jian side of He Fei
Cao Ren - Succeed in Battle Objective 2 on the Lu Bu side of Fan Castle
Diao Chan - Clear Musou Mode with 1 character from each Kingdom
Dong Zhuo - Succeed in Battle Objective 1 on the Lu Bu side of The Battle of Hu Lao Gate
Gan Ning - Clear Musou Mode with 1 Wu character
Guan Ping - Succeed in 2 battle objectives on the Shu side of Fan Castle and finish battle with Guan Ping alive
Huang Gai - Succeed in Battle Objective 3 on the Wu side of The Battle of Chi Bi
Huang Zhong - Succeed in 1 battle objective on the Wei side of Ding Jun Mountain
Ling Tong - Succeed in Battle Objective 1 on the Wei side of the Battle of Shi Ting
Liu Bei - Clear Musou Mode with 3 Shu characters
Lu Bu - Clear Musou Mode with Liu Bei, Cao Cao, Diao Chan, and Sun Jian
Lu Meng - Succeed in 2 battle objectives on the Wei side of He Fei
Ma Chao - Succeed in battle objective 2 on the Wei side of Han Zhong Attack Defense Battle
Pang Tong - Succeed in 3 battle objectives at Cheng Du battle and finish battle with Pang Tong alive
Sun Ce - Succeed in Battle Objective 1 on the Sun Jian side of the Battle of Xia Pi
Sun Jian - Clear Musou Mode with 3 Wu characters
Sun Quan - Succeed in Battle Objective 1 on the Lu Bu side of The Battle of Chi Bi
Taishi Ci - Defeat him in the Battle for Wu Territory
Wei Yan - Succeed in 2 battle objectives on the Shu side of WuZhang Plains and finish battle with Wei Yan alive
Xiahou Yuan - Succeed in 1 battle objective on the Shu side of Ding Jun Mountain
Xiao Quio - Succeed in Battle Objective 3 on the Wu side of the Battle of Shi Ting
Xu Huang - Succeed in 2 battle objectives on the Wei/Wu side of Fan Castle
Xu Zhu - He Fei, Wu side, Personally kill Cao Ren and Xu Chu
Yuan Shao - As Wei, complete all 3 targets and capture Wu Chao before completing the stage.
Yue Ying - Succeed in Battle Objective 1 on the Wei side of the Battle of Wu Zhang Plains
Zhang Jiao - Beat stage with completing all three targets in the Yellow Turban Rebellion. Playable in only Free Mode and Challenge Mode
Zhang Liao - Clear Musou Mode with 1 Wei character
Zhen Ji - Xu Du Invasion Battle, Lu Bu Scenario, succeed Battle Objective 1.
Zheng He - Succeed in 2 battle objectives on the Shu side of Han Zhong Attack Defense Battle
Zhou Tai - Succeed in 3 battle objectives on the Shu side of Yi Ling
Zhuge Liang - Clear Musou Mode with 1 Shu character