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Unlockable: Characters for Dynasty Warriors 6

The following characters can be unlocked via the techniques listed.

Cao Cao - Complete Musou mode with three Wei characters
Cao Pi - Defeat Cao Pi in less than five minutes on the Wu side of He Fei
Cao Ren - Complete Battle Objective 2 on the Lu Bu side of Fan Castle
Diao Chan - Complete Musou mode with one character from each kingdom
Dong Zhuo - Complete Musou mode as Lu Bu
Gan Ning - Complete Musou mode as a Wu character
Guan Ping - Complete Battle Objective 2 on the Shu side of Fan Castle and finish the battle with Guan Ping surviving
Huang Gai - Complete Battle Objective 3 on the Wu side of The Battle of Chi Bi
Huang Zhong - Complete Battle Objective 1 on the Wei side of Ding Jun Mountain
Ling Tong - Complete Battle Objective 1 on the Wei side of the Battle of Shi Ting
Liu Bei - Complete Musou mode with three Shu characters
Lu Bu - Complete Musou mode with Liu Bei, Cao Cao, Dio Chan and Sun Jian
Lu Meng - Complete Battle Objective 2 on the Wei side of He Fei
Ma Chao - Complete Battle Objective 2 on the Wei side of Han Zhong Attack Defense Battle
Pang Tong - Complete Battle Objective 3 at Cheng Du battle and finish the battle with Pang Tong surviving
Sun Ce - Complete Battle Objective 1 on the Sun Jian side of the Battle of Xia Pi
Sun Jian - Complete Musou mode with three Wu characters
Sun Quan - Complete Battle Objective 1 on the Lu Bu side of The Battle of Chi Bi
Taishi Ci - Defeat Taishi Ci in the Battle For Wu Territory
Wei Yan - Complete Battle Objective 2 on the Shu side of Wu Zhang Plains and finish the battle with Wei Yan surviving
Xiahou Yuan - Complete Battle Objective 1 on the Shu side of Ding Jun Mountain
Xiao Quio - Complete Battle Objective 3 on the Wu side of the Battle of Shi Ting
Xu Huang - Complete Battle Objective 2 on the Wei or Wu side of Fan Castle
Xu Zhu - On He Fei on the Wu side, personally kill Cao Ren and Xu Chu
Yue Ying - Complete Battle Objective 1 on the Wei side of the Battle of Wu Zhang Plains
Zhang Jiao - Defeat Zhang Jiao in the Yellow Turban Rebellion
Zhang Liao - Complete Musou mode as a Wei character
Zhen Ji - Complete Battle Obective 1 on Xu Du Invasion Battle, Lu Bu scenario
Zheng He - Complete Battle Objective 2 on the Shu side of Han Zhong Attack Defense Battle
Zhou Tai - Complete Battle Objective 3 on the Shu side of Yi Ling
Zhuge Liang - Complete Musou mode with a Shu character