• Aizen Sousuke - Clear Arcade Mode with Ulquiorra
  • Arturo Plateado - Clear Episode Mode with Arturo Plateado
  • Grimmjow Jaggerjack - Clear Arcade Mode with Aizen Sousuke
  • Hinamori Momo - Clear Histugaya Toushiro's Story
  • Hisago Shuuhei - Clear Episode Mode with Yamada Hanatarou
  • Ichimaru Gin - Clear Arcade Mode with both Matsumoto Rangiku and Kira Izuru
  • Kuchiki Rukia - Clear Abarai Renji's Story
  • Kurotsuchi Mayuri - Clear Arcade Mode with Ishida Uryuu
  • Kusajishi Yachiru - Clear Arcade Mode with both Yumichika Ayasegawa and Zaraki Kenpachi
  • Kyouraku Shunsui - Clear Arcade Mode with Sado Yasutora
  • Madarame Ikkaku - Clear Episode Mode with Zaraki Kenpachi
  • Shihouin Yoruichi - Clear Training Mode
  • Soi Fon - Clear Episode Mode with Shihouin Yoruichi
  • Tousen Kaname - Clear Arcade Mode with both Hisagi Shuuhei and Komamura Sajin
  • Ulquiorra - Clear Arcade Mode with both Tousen Kaname and Ichimaru Gin
  • Ukitake Juushiro - Clear Arcade Mode with Kyouraku Shunsui
  • Urahara Kisuke - Clear Arcade Mode with Kurotsuchi Mayuri
  • Yamada Hanatarou - Clear Toushiro Hitsugaya's Story
  • Yamamoto Genryuusai Shigenkuni - Clear Arcade Mode with Ukitake Juushiro
  • Yumichika Ayasegawa - Clear Arcade Mode with Madarame Ikkaku